Examines the mechanisms and macrokinetic features of mechanical fracture. Quantum chemical calculations of the effect of loading on reactivity are presented and the rules governing fracture in micromechanically differing models are compared. Crack growth, the thermal decomposition of ammonium perchlorate and low temperature chain halogenation are described.<br>Heterocyclization reactions of b-unsaturated P(III) compounds with reagents carrying 1,2-or 1,3-placed electrophilic and nucleophilic centers are reviewed. The conditions for the formation of intermediate cyclic ylides and their conversion into stable end products are discussed and mechanisms are suggested for the reactions under review.
| Title: | a, b- Unsaturated Derivatives of Trivalent Phosphorous in the Synthesis of Heterocycles (Soviet Scientific Reviews Series, Section B) (Vol 15, Part 5) | Publisher: | Routledge |
| Author: | G B Manelis |
| Edition: | Paperback 1 |
| ISBN: | 3718651181 |
| EAN: | 9783718651184 |
| No. of Pages: | 101 |
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